[1,3] And [3,3] rearrangements of 3-amino-1,5-hexadienes: Solvent effect on the regioselectivity

DOI: 10.1016/S0040-4039(99)00455-4

Source and publish data:

Tetrahedron Letters p. 3119 - 3122 (1999)

Update date:2022-07-30

Topics:

Authors:

Dobson, Heather K.

LeBlanc, Richard

Perrier, Helene

Stephenson, Corey

Welch, Teresa R.

Macdonald, Dwight

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Article abstract of DOI:10.1016/S0040-4039(99)00455-4

3-Amino-1,5-Hexadienes rearrange under anionic conditions to give a [1,3] product in addition to the [3,3] (Cope) product. With some substrates the regioselectivity of the reaction is strongly influenced by the solvent polarity.

Full text of DOI:10.1016/S0040-4039(99)00455-4

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