Tetrahedron Letters p. 5917 - 5920 (1995)
Update date:2022-08-04
Topics:
Seto, Hideharu
Sassa, Takeshi
Kawaide, Hiroshi
Shigihara, Takashi
Uzawa, Jun
Yoshida, Shigeo
A 17-hydroxy-16β, 17-dihydrogibberellin, GA829, was first isolated from a fungus, Phaeosphaeria sp. L487, and was synthesized from naturally abundant GA41 in a highly stereocontrolled manner whose essential step was inversion of C(16) configuration of readily accessible 16β-formyl intermediate 5 to more stable 16α-epimer 6 by base treatment.
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