Design and synthesis of the basic Cu-doped zeolite X catalyst with high activity in oxidative coupling reactions

Article abstract of DOI:10.1016/j.jcat.2016.01.030

The decarboxylative coupling of cinnamic acids with alcohols and the oxidative coupling of alkenes with aldehydes are typical organic reactions. Considering the characteristics and mechanisms of the reactions, the Cu-doped zeolite-X catalyst (Cu-X) with Lewis basic sites was synthesized and used for the two reactions. Compared with Cu, Cu₂O, and CuBr₂ catalysts (4-21%), the Cu-X catalyst (99%) shows extraordinary high activity in the decarboxylative coupling of cinnamic acids with alcohols. In addition, the Cu-X catalyst presents excellent performance in the oxidative coupling of alkenes with aldehydes. The strong interaction between Cu⁺ and the zeolite framework benefits the transformation of Cu²⁺ and Cu⁺ in the redox process, enhancing the reaction activity. More importantly, the Lewis basic sites on the Cu-X catalyst could favor the adsorption of the cinnamic acid, resulting in electron-rich density in the C=C bond, and therefore greatly improving the reaction activity.