Chemistry Letters p. 348 - 349 (2004)
Update date:2022-08-03
Topics:
Narahashi, Hirohisa
Yamamoto, Akio
Shimizu, Isao
A new synthetic method for 1-aryl-2-alkenes from 1-olefins by benzylation treating with benzyl trifluoroacetates using palladium-catalyst is developed on the basis of oxidative addition of benzyl carboxylates to Pd(0) complexes to give benzyl(carboxylato)palladium(II) complexes with cleavage of benzyl-oxygen bond.
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