Tetrahedron p. 4595 - 4620 (1999)
Update date:2022-08-05
Topics:
Nakamura, Yutaka
Takeuchi, Seiji
Ohgo, Yoshiaki
Yamaoka, Makoto
Yoshida, Akihiro
Mikami, Koichi
SmI2-mediated reductive cleavage of α-heterosubstituents of α-alkyl or α-aryl ketones and lactone gave the corresponding 'thermodynamic samarium enolates'. Enantioselective protonation of the samarium enolates with C2- symmetric chiral diols afforded the corresponding ketones and lactone in moderate to high enantioselectivities.
View MoreShenzhen Feiming Science and Technology Co,. Ltd
Contact:+86-755-85232577
Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
Dalian RSD International Trade Co.,Ltd.(expird)
Contact:86-22-60875058 58610575
Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Chengda Pharmaceuticals Co., Ltd.
Contact:+86-573-84601188
Address:hengshan Road 5# in Jiashan, zhejiang
Shanghai Yudiao Chemistry Technology Co.,Ltd
Contact:0086-18964703211
Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
Shanghai PotentPharm Science and Technology Co.,Ltd
Contact:86-021-51969655
Address:Unit B, Building 18, No.300, Chuantu Rd,Pudong District, Shanghai 201202, China
Doi:10.1038/s41586-018-0366-x
(2018)Doi:10.1016/S0014-827X(01)01197-1
(2002)Doi:10.1016/S0040-4039(00)00048-4
(2000)Doi:10.1248/cpb.16.414
(1968)Doi:10.1007/BF01167269
(1971)Doi:10.1002/anie.201814660
(2019)
