Bioscience, Biotechnology and Biochemistry p. 1934 - 1941 (1999)
Update date:2022-09-26
Topics: Stereoisomers Total syntheses
Toshima, Hiroaki
Saito, Masatoshi
Yoshihara, Teruhiko
All four stereoisomers of (2S, 3R)-(+)-piscidic acid were synthesized with high optical purity via Sharpless catalytic asymmetric dihydroxylation of (Z)- and (E)-trisubstituted olefins in 6 steps from (4-hydroxyphenyl)pyruvic acid. The Wittig reaction of
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(2019)
