Synthesis of C-glycosides via radical cyclization reactions with a vinylsilyl tether. Control of the reaction course by a change in the conformation of the pyranose ring due to steric repulsion between adjacent bulky protecting groups

DOI: 10.1016/S0040-4039(99)01026-6

Source and publish data:

Tetrahedron Letters p. 5527 - 5531 (1999)

Update date:2022-08-02

Topics:

Authors:

Yahiro, Yumi

Ichikawa, Satoshi

Shuto, Satoshi

Matsuda, Akira

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Article abstract of DOI:10.1016/S0040-4039(99)01026-6

A stereoselective method for introducing a C2-unit at the 1α- and 1β- postions of D-glucose and D-mannose, respectively, via a radical cyclization reaction with vinylsilyl group as a temporary connecting tether, was developed. The radical cyclization of D

Full text of DOI:10.1016/S0040-4039(99)01026-6

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Product name:phenyl 3,4,6-tris(O-tert-butyldimethylsilyl)-1-seleno-α-D-glucopyranoside

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