Tetrahedron p. 7191 - 7208 (1999)
Update date:2022-08-04
Topics:
Bollbuck, Birgit
Tochtermann, Werner
A number of bicyclic macrolides with two stereogenic centres formally derived from ω-cycloalkyl fatty acids were synthesised by ring enlargement of cycloalkanones with novel chiral building blocks, easily available from yeast reduction products of β-keto esters. A comparison with structurally related monocyclic macrolides revealed surprising effects of structural variations on the olfactory properties.
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