Tetrahedron Letters p. 3913 - 3916 (1999)
Update date:2022-07-30
Topics:
Aguilar, Nuria
Moyano, Albert
Pericas, Miquel A.
Riera, Antoni
The totally enantiocontrolled preparation of C2-symmetrical and pseudosymmetrical sulfur-tethered bis(amino alcohols) from anti-3-amino-1,2- alkane diols is described. The key step in the synthetic procedure involves the use of triphenylsilanethiol as a sulfide or hydrogenosulfide equivalent in the regioselective nucleophilic ring opening of both anti- and syn- aminoalkyl epoxides.
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Doi:10.1016/S0022-328X(99)00206-5
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(1969)
