Platinum(II) chloride complexes of linear alkyl-bridged 2,2′-bipyridine/catechol ligands

DOI: 10.1002/(SICI)1521-3749(199908)625:8<1343::AID-ZAAC1343>3.0.CO;2-H

Source and publish data:

Zeitschrift fur Anorganische und Allgemeine Chemie p. 1343 - 1348 (1999)

Update date:2022-08-05

Topics:

Authors:

Albrecht, Markus

Riether, Cyrill

Froehlich, Roland

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Article abstract of DOI:10.1002/(SICI)1521-3749(199908)625:8<1343::AID-ZAAC1343>3.0.CO;2-H

Platinum(II) chloride can selectively be coordinated to the 2,2′-bipyridine moiety of the alkyl bridged sequential catechol/2,2′-bipyridine ligand 1 a-H₂ and of the related ligands 1a/b-Me₂ and 2. Reaction of (1b-Me₂)PtCl₂ with BBr₃ produces the platinum(II) complex (1b-H₂)PtCl₂ while ether cleavage of the uncoordinated ligand 1b-Me₂ fails. Under basic conditions (1a-H₂)PtCl₂ forms polymeric/ oligomeric species [(1a)Pt]_n besides traces of the dinuclear complex [(1a)Pt]₂.

Full text of DOI:10.1002/(SICI)1521-3749(199908)625:8<1343::AID-ZAAC1343>3.0.CO;2-H

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