Tetrahedron Letters p. 5083 - 5086 (1999)
Update date:2022-07-30
Topics:
Esteve, Cristina
Ferrero, Monica
Romea, Pedro
Urpi, Felix
Vilarrasa, Jaume
Titanium-mediated aldol reactions of 1 and (S)-2-tert- butyldiphenylsilyloxy aldehydes (matched pair) afford syn Felkin diastereomers in excellent yield and absolute stereochemical control. Having established that chain length does not affect the yield of the titanium aldol reactions, we have been able to achieve short, high yielding and enantioselective syntheses of NFX-2 and Antimycinone.
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Doi:10.1039/c7ob02012k
(2017)Doi:10.1002/ardp.202100102
(2021)Doi:10.1016/S0968-0896(99)00101-7
(1999)Doi:10.1016/S0040-4039(97)00052-X
(1997)Doi:10.1016/0040-4039(95)01990-Y
(1995)Doi:10.1021/jo990112c
(1999)
