
Tetrahedron Letters p. 7039 - 7042 (1999)
Update date:2022-07-30
Topics:
Turner, John J.
Wilschut, Niels
Overkleeft, Herman S.
Klaffke, Werner
Van der Marel, Gijs A.
Van Boom, Jacques H.
Amino-acid derived 2-nitrobenzenesulfonamides were successfully condensed under Mitsunobu conditions with 2,3,4,6-tetra-O-acetyl-D-glucose to afford the fully protected glucosylamines in excellent yield. Upon total deprotection, these compounds rearranged to provide the corresponding Amadori products in good overall yield.
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