
Tetrahedron p. 9999 - 10004 (1999)
Update date:2022-08-04
Topics:
Coetzee, Johan
Malan, Elfranco
Ferreira, Daneel
Treatment of 4β-chloroepioritin tri-O-methylether with phenylmethanethiol under neutral conditions affords both the 4α- and 4β- substituted epioritin derivatives. The stereochemical course of the reaction is of relevance to the thiolysis of 5-oxy (A-ring)
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