Synthesis of 18-demethyltaxoid via stereoselective allylation and intramolecular aldol condensation reactions

DOI: 10.1246/cl.1999.817

Source and publish data:

Chemistry Letters p. 817 - 818 (1999)

Update date:2022-08-04

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Authors:

Iwadare, Hayato

Sakoh, Hiroki

Arai, Hidehiro

Shiina, Isamu

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1999.817

Optically active novel 18-demethyltaxiods were successfully synthesized from 2α,10β-dibenzyloxy-11β-(t-butyldimethylsiloxy)-7β-hydroxy-1 α-(p-methoxybenzyloxy)-8β,15,15-trimethyl-4-methylene-trans-bicyclo[6 .4.0]dodecan-9-one (2) which corresponds to the

Full text of DOI:10.1246/cl.1999.817

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