Synthesis of novel glycosyl phosphate analogues: Derivatives of an acceptor substrate for the Leishmania elongating α-D-mannopyranosylphosphate transferase

Article abstract of DOI:10.1016/S0040-4039(99)01381-7

The three structural analogues of dec-9-enyl β-D-galactosyl-(l→4)-α- D-mannosyl phosphate, comprising thiophosphate, boranophosphate and methylphosphonate derivatives, were prepared via disaccharide H-phosphonate or trichloroacetimidate (for the methylphosphonate synthesis) intermediates.