A general synthesis of vinylic silyl hydrides using nickel catalysis. Applications to the syntheses of silylene-tethered conjugated polymers

DOI: 10.1016/S0040-4020(97)10218-6

Source and publish data:

Tetrahedron p. 1197 - 1206 (1998)

Update date:2022-08-05

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Authors:

Chen, Ruey-Min

Luh, Tien-Yau

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Article abstract of DOI:10.1016/S0040-4020(97)10218-6

Treatment of benzylic or allylic dithioacetals with Me₂((i)PrO)SiCH₂MgCl in the presence of NiCl₂(PPh₃)₂ catalyst yielded the corresponding i-propoxy(vinyl)silanes which are reduced with LiAlH_{4
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Full text of DOI:10.1016/S0040-4020(97)10218-6

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