Synthesis and reactions of highly sterically hindered organosilicon compounds of the type (Me3Si)3CSi(C6H4-OMe-p)MeX and (Me3Si)3CSi(C6H4-Me-p)MeX

Article abstract of DOI:10.1080/10426509908037034

Direct nucleophilic displacement of TsiSi(C₆H₄-OMe-p)MeI and TsiSi(C₆H₄Me-p)MeI with nucleophiles take place. These compounds also react with electrophiles such as AgOAc and AgNO₃ to give rearrangment products, for example (Me₃Si)₂C(SiMe₂OAC)SiMe₂ (C₆H₄-Y-P) (Y = Me, OMe). The hydrides and bromides of these compounds were also synthesised.

Full text of DOI:10.1080/10426509908037034

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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SYNTHESIS AND REACTIONS
OF HIGHLY STERICALLY
HINDEREID ORGANOSILICON
COMPOUNDS OF THE TYPE
(Me3Si)3CSi(C6H4-OMe-p)MeX
AND (Me3Si)3CSi(C6H4-Me-p)MeX
Kazem D. Safa a , Mohammad Bolourtchlan a &
Mohammad G. Asadi a
a Faculty of chemistry , University of Tabriz , Tabriz,
Iran
Published online: 24 Sep 2006.
To cite this article: Kazem D. Safa , Mohammad Bolourtchlan & Mohammad G. Asadi
(1999) SYNTHESIS AND REACTIONS OF HIGHLY STERICALLY HINDEREID ORGANOSILICON
COMPOUNDS OF THE TYPE (Me3Si)3CSi(C6H4-OMe-p)MeX AND (Me3Si)3CSi(C6H4-Me-
p)MeX, Phosphorus, Sulfur, and Silicon and the Related Elements, 149:1, 229-236, DOI:
10.1080/10426509908037034
To link to this article: http://dx.doi.org/10.1080/10426509908037034
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