Tetrahedron Letters p. 7779 - 7782 (1999)
Update date:2022-08-02
Topics:
Millot, Nicolas
Knochel, Paul
Highly substituted cyclic allylzinc reagents 2 have been prepared by fragmentation of sterically hindered homoallylic zinc alcoholates 1. Their reactions with aldehydes proceed under mild conditions and are highly stereoselective (64-86% ; d.r. up to >98/2). Examples of acylation with benzonitrile and zinc-ene cyclization giving new spirobicyclic zinc reagents are also reported.
View MoreAnyang Double Circle Auxiliary CO.,LTD
Contact:0086-134 6082 4403
Address:dongfeng road, anyang city, henan province,china
Jiangxi Dongbang Pharmaceutical Co., Ltd.
Contact:+86-795-4433603, 4433388
Address:Fengxin Industrial Park, Fengxin County, Jiangxi Province, P.R.C
Nanjing lanbai chemical Co.,Ltd.
Contact:+86-25-85499326
Address:Room 908, 9F Taiyue Building,No.285 Heyan Road
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.
Contact:86-022-89880739
Address:10B, Pan China International Center, No. 931 YingKou Road, TangGu, Tianjin, China, 300451
Shandong Hongxiang Zinc Co., Ltd
Contact:086-0311-66187879
Address:DaWang developing zone
Doi:10.1016/j.tet.2016.03.004
(2016)Doi:10.1016/j.mcat.2020.111124
(2020)Doi:10.1039/c39900000980
(1990)Doi:10.1021/ja00177a029
(1990)Doi:10.1016/j.bmc.2011.02.021
(2011)Doi:10.1039/c0ob00807a
(2011)