Synthesis of functional olefins using the Wittig-Horner reaction in different media

Article abstract of DOI:10.1080/00397919908085894

A convenient procedure for the synthesis of E-olefins bearing electron donor-acceptor groups is reported. A new diethyl N-aryl aminobenzylphosphonate (1d) was synthesized. Reactivity of Wittig-Horner reaction is compared. Expansion of the π-conjugate chain involves the reduction of N-methoxy-N-methyl amide to aldehyde by reaction with DIBAL-H.

Full text of DOI:10.1080/00397919908085894

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Synthetic Communications: An
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Synthesis of Functional Olefins
Using the Wittig-Horner Reaction in
Different Media
Edgardo N. Durantini a
a Departamento de Química y Física, Universidad Nacional
de Río Cuarto, Agencia Postal Nro 3, Río Cuarto, 5800,
Argentina E-mail:
Published online: 17 Sep 2007.
To cite this article: Edgardo N. Durantini (1999) Synthesis of Functional Olefins Using the
Wittig-Horner Reaction in Different Media, Synthetic Communications: An International
Journal for Rapid Communication of Synthetic Organic Chemistry, 29:23, 4201-4222
To link to this article: http://dx.doi.org/10.1080/00397919908085894
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