A Horner-Wittig approach of S,N-ketene acetals. Acid-catalyzed hydrolysis of S,N-ketene acetals to (S)-thioesters

DOI: 10.1016/0040-4020(96)00626-6

Source and publish data:

Tetrahedron p. 11095 - 11104 (1996)

Update date:2022-08-04

Topics:

Authors:

Otten, Pieter A.

Oskam, Njord

Van Der Gen, Arne

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Article abstract of DOI:10.1016/0040-4020(96)00626-6

The synthesis of S,N-acetals of formyldiphenylphosphine oxide 2 is described. The stable lithiated anions of these acetals were applied in a Horner-Wittig reaction with several structural types of aldehydes. The resulting S,N-ketene acetals 1 were obtaine

Full text of DOI:10.1016/0040-4020(96)00626-6

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