An effective method for the preparation of optically active polyoxy 8-membered ring enone corresponding to the B ring of taxol

DOI: 10.1246/cl.1999.1145

Source and publish data:

Chemistry Letters p. 1145 - 1146 (1999)

Update date:2022-09-26

Topics:

Authors:

Shiina, Isamu

Shibata, Jun

Imai, Yumiko

Ibuka, Ryoutarou

Fujisawa, Hidehiko

Hachiya, Iwao

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1999.1145

An effective method for the preparation of 8-membered ring enone 1 in sufficient quantities was developed. First, optically active trialkoxyaldehyde 3 was prepared by diastereoselective dihydroxylation of olefin 7 derived from D-pantolactone. Secondly, 8-

Full text of DOI:10.1246/cl.1999.1145

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