Journal of Organic Chemistry p. 2813 - 2816 (1980)
Update date:2022-08-04
Topics:
Sauers, Ronald R.
Weston, Charles A.
Dentz, Bernard I.
New 2,2-substituted derivatives of tricyclo<3.2.1.03.6>octane with the following sets of substituents were synthesized in a study designed to test their stability toward Wagner-Meerwein rearrangements: CH3, OH; CH3, Cl; C6H5, OH; Cl, Cl; Br, CO2H.Epimerizations, but not skeletal rearrangements, were observed in some cases.The phenyl carbinol underwent self-reduction under vigorous conditions.
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