Reactions of Phosphine, arsine, and Stibine with Carbonylbis(triethylphosphine)iridium(I) Halides. Part 1. Reactions in Toluene; X-Ray Crystal Structures of and 6-MeC6H4CHMe2-p)> (X=Br, Z=P; X=Cl, Z=As)

DOI: 10.1039/DT9870002831

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2831 - 2838 (1987)

Update date:2022-08-03

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Authors:

Ebsworth, E. A. V.

Gould, Robert O.

Mayo, Richard A.

Walkinshaw, Malcolm

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Article abstract of DOI:10.1039/DT9870002831

trans- (X=Br or Cl) reacts with ZH3 (Z=P, As, or Sb) in toluene at 180 K to give .When Z=P or As, the product is monoisomeric, but with Z=Sb two isomers are formed.. (4) reacts with Cl2 to give ; with Se, is the product.Reaction with HCl at 200 K gives (1+), but as the solution is allowed to warm PH3 is displaced by Cl, and a similar reaction with H2Se leads to the formation of .Boron trifluoride does not interact with (4), but B2H6 reacts to give a BH3 adduct that is stable in solution at room temperature.Compound (4) reacts with <6-MeC6H4CHMe2-p)>2>, forming 6-MeC6H4CHMe2-p)>.Reactions of (5) are similar, except that treatment with Se leads to decomposition.The crystal structures of (5) and the complexes formed by both (4) and (5) with <6-MeC6H4CHMe2-p)>2> are reported.

Full text of DOI:10.1039/DT9870002831

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