Inorganic Chemistry p. 964 - 967 (1972)
Update date:2022-08-05
Topics:
Barefield
Parshall
Interactions between the central rhodium and ligand C-H bonds leading to exchange of hydrogen for deuterium have been observed in [(C6H5O)3P]3RhCl and [(C6H5O)3P]4Rh+. In [(C6H5O)3P]4Rh+ this exchange is preceded by oxidative addition of hydrogen and an equilibrium loss of a proton. Reaction of [(C6H5O)3P]3RhCl with phenylmagnesium chloride produces an air-sensitive ortho-bonded complex [(C6H5O)3P]2(C6H 5O)2POC6H4Rh. Reactions of this complex with H2, DCl, CO, and excess (C6H5O)3P are reported.
Landz International Company Ltd.
Contact:0086-21-58891610
Address:985 Dongfang Road, Pudong, Shanghai 200122 China
website:http://www.eastarchem.com/
Contact:1-800-898-2436
Address:1215 K Street, STE 1700
Shanghai Dano Pharmaceutical Co.,Ld.(expird)
Contact:+86-592-6266840
Address:Building 1 Room 512, 720 Cailun Rd, Zhangjiang High-Tech Park, Shanghai 201203, China
Wuhan Shangrisyn chemicals Technology Co.,Ltd(expird)
Contact:+86-027-84466317 __ +86-15387123698
Address:wuhan - china
Chongqing maohuan Chemicals Co., Ltd
website:http://www.bschem.com
Contact:+86 13996103726
Address:Chongqing Nan'an District Tu Town
Doi:10.1016/j.tet.2008.07.085
(2008)Doi:10.1080/00377310209517656
(1946)Doi:10.1021/om990734o
(2000)Doi:10.1038/nchem.1351
(2012)Doi:10.1021/jo991364g
(2000)Doi:10.1021/ja01375a058
(1930)
