Inorganic Chemistry p. 964 - 967 (1972)
Update date:2022-08-05
Topics:
Barefield
Parshall
Interactions between the central rhodium and ligand C-H bonds leading to exchange of hydrogen for deuterium have been observed in [(C6H5O)3P]3RhCl and [(C6H5O)3P]4Rh+. In [(C6H5O)3P]4Rh+ this exchange is preceded by oxidative addition of hydrogen and an equilibrium loss of a proton. Reaction of [(C6H5O)3P]3RhCl with phenylmagnesium chloride produces an air-sensitive ortho-bonded complex [(C6H5O)3P]2(C6H 5O)2POC6H4Rh. Reactions of this complex with H2, DCl, CO, and excess (C6H5O)3P are reported.
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(1930)
