Journal of Organic Chemistry p. 840 - 844 (1992)
Update date:2022-08-02
Topics:
Krosley, Kevin W.
Gleicher, Gerald Jay
Clapp Gary E.
The four isomers of chloroepoxypropane have been prepared, and their relative reactivities with triphenyltin haydride have been determined.The three α-chloroepoxypropanes react at a much slower rate than does epichlorohydrin, the only β-chloro epoxide of the four.The nature of the increased reactivity for the β-chloro epoxides has been investigated by studying two pair of diastereomeric β-chloro epoxides, and a single acyclic β-chloro ether.The results are discussed in terms of the inductive, and stereoelectronic effects of the epoxide.
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