Peri-interactions in naphthalenes, 21. Substituent effects in (8-dimethylamino-naphth-1-yl)-and [2-(dimethylamino-methyl)phenyl]-phosphines on the 31P-NMR signal positions

Article abstract of DOI:10.1080/10426500008046619

Contrary to claims in the literature, the ³¹P NMR signal positions of ortho-dimethylaminomethyl-substituted triarylphosphines do not provide evidence for hypercoordination at phosphorus; the observed highfield shifts relative to triphenylphosphine are rather due to the ortho-effect. In (8-dimethylamino-naphth-1-yl)phosphines, the signal positions similar to that of triphenylphosphine are the result of the highfield ortho-effect and a lowfield peri-substituent effect of about the same magnitude whose nature remains to be explored.

Full text of DOI:10.1080/10426500008046619

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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PERI-INTERACTIONS IN
NAPHTHALENES, 21.
SUBSTITUENT EFFECTS IN (8-
DIMETHYLAMINO-NAPHTH-1-
YL)- AND [2-DIMETHYLAMINO-
METHYL)PHENYL] -
PHOSPHINES ON THE 31P-NMR
SIGNAL POSITIONS
Günter Paulus Schiemenz a
a Institut für Organische Chemie der Universität ,
0-24098, Kid, Germany
Published online: 04 Oct 2006.
To cite this article: Günter Paulus Schiemenz (2000) PERI-INTERACTIONS IN
NAPHTHALENES, 21. SUBSTITUENT EFFECTS IN (8-DIMETHYLAMINO-NAPHTH-1-YL)-
AND [2-DIMETHYLAMINO-METHYL)PHENYL] - PHOSPHINES ON THE 31P-NMR SIGNAL
POSITIONS, Phosphorus, Sulfur, and Silicon and the Related Elements, 163:1, 185-202,
DOI: 10.1080/10426500008046619
To link to this article: http://dx.doi.org/10.1080/10426500008046619
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