Synthesis of peptides with α,β-dehydroamino acids. XIII photoisomerization of Ac-(Z)-ΔpHe-NHMe: Ac-(E)-ΔPhe-NHMe

DOI: 10.1248/cpb.48.296

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 296 - 297 (2000)

Update date:2022-08-05

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Authors:

Kubica, Zbigniew

Kozlecki, Tomasz

Rzeszotarska, Barbara

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Article abstract of DOI:10.1248/cpb.48.296

Easily accessible Ac-(Z)-ΔPhe-NHMe was photoisomerized to so far unknown Ac-(E)-ΔPhe-NHMe. Some parameters of the process leading to a diastereomeric mixture of ratio 90(Z): 10(E) have been tested and the photoisomerization has been carried out on a preparative milligram scale. The isomers were separated via crystallization followed by preparative HPLC.

Full text of DOI:10.1248/cpb.48.296

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