Chemistry - A European Journal p. 1500 - 1504 (2014)
Update date:2022-07-31
Topics:
Rouse, Kevin
Schneider, Cdric
Couve-Bonnaire, Samuel
Pannecoucke, Xavier
Levacher, Vincent
Hoarau, Christophe
Pd/Cu-catalyzed decarboxylative/direct C-H alkenylations of heteroarenes with α-fluoroacrylic acid is reported. This method offers step-economical and stereocontrolled access to valuable heteroarylated monofluoroalkenes as both Z and E isomers, which are known to be useful in the synthesis of fluorinated biomolecules.
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