
Journal of the Chemical Society. Chemical communications p. 993 - 994 (1995)
Update date:2022-08-04
Topics:
Derouane, Daphne
Harvey, Jeremy N.
Viehe, Heinz G.
The title reactions can be explained by Wagner-Meerwein rearrangement of α-thio carbocations (thionium ions) to β-thio carbocations; this unusual reactivity may be due to superelectrophilic activation by aluminium chloride.
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