Effect of an Alkynyl Group on the Regio- and Stereochemistry of the Ring Opening of 1,2-Epoxides. Ring-Opening Reactions of 1-Ethenyl-1,2-epoxycyclohexane

DOI: 10.1021/jo00315a039

Source and publish data:

Journal of Organic Chemistry p. 434 - 438 (1981)

Update date:2022-08-02

Topics:

Authors:

Battistini, Carlo

Crotti, Paolo

Macchia, Franco

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00315a039

The regio- and stereochemistry of the ring-opening reactions of 1-ethenyl-1,2-epoxycyclohexane (1) under acidic conditions have been examined.The reactions were almost completely regiospecific, giving mainly products arising from attack by nucleophile on

Full text of DOI:10.1021/jo00315a039

Products guided by the article

Product name:Cyclohexanol, 1-ethynyl-2-methoxy-, trans-

Cas No:28144-12-9

R&D Labs maybe for 28144-12-9

taicang liyuan chemical co,.ltd

website:http://www.tcliyuanchem.com/productse.php

Contact:86-512-53539583

Address:Room 804,Huaxu Building,No.95,Renmin South Road,Taicang city,Jiangsu Province,China
LIDE PHARMACEUTICALS LIMITED

website:http://www.lidepharma.com

Contact:+86-25-58409506

Address:Chungking Express Nos.36 Nathan Road，Kowloon, HK
Xi'an caijing Opto-Electrical Science & Technology Co., LTD

Contact:+86-29-88294447

Address:NO.168 Zhangba Rd. East, Xi'an, P.R.China
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China

Relevant to this article

Oxidation of Sulfides by Acyclic α-Azohydroperoxides

Doi:10.1021/jo00149a014
(1983)
SYNTHESIS OF L-IDARO-1,4-LACTONE, AN INHIBITOR OF α-L-IDOSID-URONASE

Doi:10.1016/S0008-6215(00)80972-6
(1982)
Molecular and electronic structures of bis(pyridine-2,6-diimine)metal complexes [ML₂](PF₆)(n) (n = 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)

Doi:10.1021/ic000113j
(2000)
Doi:10.1021/jo00809a021
(1971)
Doi:10.1246/bcsj.43.1586
(1970)
1,2-asymmetric induction in the conjugate addition of organocopper reagents to γ-aryl α,β-unsaturated carbonyl derivatives

Doi:10.1016/S0040-4020(00)00137-X
(2000)

Article Doi