Effect of an Alkynyl Group on the Regio- and Stereochemistry of the Ring Opening of 1,2-Epoxides. Ring-Opening Reactions of 1-Ethenyl-1,2-epoxycyclohexane

DOI: 10.1021/jo00315a039

Source and publish data:

Journal of Organic Chemistry p. 434 - 438 (1981)

Update date:2022-08-02

Topics:

Authors:

Battistini, Carlo

Crotti, Paolo

Macchia, Franco

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00315a039

The regio- and stereochemistry of the ring-opening reactions of 1-ethenyl-1,2-epoxycyclohexane (1) under acidic conditions have been examined.The reactions were almost completely regiospecific, giving mainly products arising from attack by nucleophile on

Full text of DOI:10.1021/jo00315a039

Products guided by the article

Product name:Cyclohexanol, 1-ethynyl-2-methoxy-, trans-

Cas No:28144-12-9

R&D Labs maybe for 28144-12-9

JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
AUSHUN PHARMACEUTICAL TECHNOLOGY CO,.LTD

Contact:+86-25-86883560 15951806178

Address:14 Dayingbi, Zhujiang Rd. East, Nanjing, Jiangsu, China.
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section

Relevant to this article

Oxidation of Sulfides by Acyclic α-Azohydroperoxides

Doi:10.1021/jo00149a014
(1983)
SYNTHESIS OF L-IDARO-1,4-LACTONE, AN INHIBITOR OF α-L-IDOSID-URONASE

Doi:10.1016/S0008-6215(00)80972-6
(1982)
Molecular and electronic structures of bis(pyridine-2,6-diimine)metal complexes [ML₂](PF₆)(n) (n = 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)

Doi:10.1021/ic000113j
(2000)
Doi:10.1021/jo00809a021
(1971)
Doi:10.1246/bcsj.43.1586
(1970)
1,2-asymmetric induction in the conjugate addition of organocopper reagents to γ-aryl α,β-unsaturated carbonyl derivatives

Doi:10.1016/S0040-4020(00)00137-X
(2000)

Article Doi