Synthesis and characterization of a new cyclobutane-substituted Schiff base ligand and its Co(II), Cu(II) and Ni(II) complexes

Article abstract of DOI:10.1080/00945710009351803

A new ligand, 4-(1-phenyl-1-methylcyclobutane-3-yl)-2-(2-hydroxy-5-bromo) benzylideneaminothiazole (LH), has been synthesized starting from 1-phenyl-1-methyl-3-(2-chloro-1-oxoethyl)cyclobutane, thiourea and 2-hydroxy-5-bromobenzaldehyde. Mononuclear complexes with a metal-ligand ratio of 1:2 have been prepared with Co(II), Cu(II), and Ni(II). Attempts to prepare the Cd(II) complex of the ligand in different solvents have failed. The authenticity of the ligand and its complexes was established based on elemental analyses, IR, ¹³C and ¹H NMR spectra, UV-Vis, magnetic susceptibility measurements and thermogravimetric analyses (TGA).

Full text of DOI:10.1080/00945710009351803

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Synthesis and Characterization
of a New Cyclobutane-
Substituted Schiff Base Ligand
and its Co(II), Cu(II) and Ni(II)
Complexes
Alaaddin Çukurovali a , Ibrahim Yilmaz a & Misir
Ahmedzade a
a Firat University, Faculty of Arts and Sciences,
Chemistry Department , 23119, Elazig, Turkey
Published online: 23 Apr 2008.
To cite this article: Alaaddin Çukurovali , Ibrahim Yilmaz & Misir Ahmedzade (2000)
Synthesis and Characterization of a New Cyclobutane-Substituted Schiff Base Ligand
and its Co(II), Cu(II) and Ni(II) Complexes, Synthesis and Reactivity in Inorganic and
Metal-Organic Chemistry, 30:5, 843-853, DOI: 10.1080/00945710009351803
To link to this article: http://dx.doi.org/10.1080/00945710009351803
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