Synthesis of tBu3E+ nitrile complexes by oxidative cleavage of tBu3E-EtBu3 (E = Si, Ge, Sn)

DOI: 10.1246/cl.2000.600

Source and publish data:

Chemistry Letters p. 600 - 601 (2000)

Update date:2022-08-03

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Authors:

Ichinohe, Masaaki

Fukui, Hiroshi

Sekiguchi, Akira

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Article abstract of DOI:10.1246/cl.2000.600

The reaction of hexa-tert-butyldimetallanes (^tBu₃E-E^tBu₃; E = Si, Ge, Sn) with trityl tetraarylborates in pivalonitrile or acetonitrile gave tri-terf-butylmetalyl cation nitrile complexes, [^tBu_3<

Full text of DOI:10.1246/cl.2000.600

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Product name:[(tert-butyl)3Sn(pivalonitrile)][tetrakis[3,5-bis(trifluoromethyl)phenyl]borate]

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