Syntheses of optically active trifluoronorcoronamic acids.

DOI: 10.1021/ol0059955

Source and publish data:

Organic letters p. 2423 - 2425 (2000)

Update date:2022-08-04

Topics:

Authors:

Katagiri

Irie Irie

Uneyama Uneyama

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Article abstract of DOI:10.1021/ol0059955

Syntheses of optically active trifluoronorcoronamic acid 6 and its diastereomer 9 are described. Highly stereospecific and diastereoselective S(N)2 cyclization of gamma-cyanohydrins 3a and 3b gave cyclopropyl nitriles 4a and 4b. Hydrolysis of the cyano gr

Full text of DOI:10.1021/ol0059955

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