Generation of Aziridinyllithiums from Sulfinylaziridines by the Ligand Exchange Reaction of Sulfoxides with tert-Butyllithium: Their Properties and An Application to Asymmetric Synthesis of α-Dialkylamino Acid Ester

DOI: 10.1016/S0040-4039(98)00150-6

Source and publish data:

Tetrahedron Letters p. 2345 - 2348 (1998)

Update date:2022-08-03

Topics:

Authors:

Satoh, Tsuyoshi

Ozawa, Masaki

Takano, Koji

Kudo, Masabumi

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Article abstract of DOI:10.1016/S0040-4039(98)00150-6

Aziridinyllithiums were generated from sulfinylaziridines by the ligand exchange reaction of sulfoxides with tert-butyllithium.The aziridinyllithiums were found to be stable in THF at below -30 deg C and reactive with several electrophiles such as carbony

Full text of DOI:10.1016/S0040-4039(98)00150-6

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