Ligand Field Transitions and the Origin of Zero Field Splitting in and (R=2,3,5,6-Me4C6H): A Model for High-Spin Fe(III) Site in Rubredoxin

DOI: 10.1021/ja00226a047

Source and publish data:

Journal of the American Chemical Society p. 6241 - 6243 (1988)

Update date:2022-08-04

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Authors:

Deaton, Joseph C.

Gebhard, Matthew S.

Koch, Stephen A.

Millar, Michelle

Solomon, Edward I.

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Article abstract of DOI:10.1021/ja00226a047

We report the assignment of LF (ligand field) transitions, for a Rb model complex (Fe(SR)^- R=2,3,5,6-Me4C6H), with single crystal polarized absorption and magnetic circular dichroism (MCD).We also experimentally test Griffith's ZFS (zero field splitting) model.

Full text of DOI:10.1021/ja00226a047

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