Ligand Field Transitions and the Origin of Zero Field Splitting in and (R=2,3,5,6-Me4C6H): A Model for High-Spin Fe(III) Site in Rubredoxin

DOI: 10.1021/ja00226a047

Source and publish data:

Journal of the American Chemical Society p. 6241 - 6243 (1988)

Update date:2022-08-04

Topics:

Authors:

Deaton, Joseph C.

Gebhard, Matthew S.

Koch, Stephen A.

Millar, Michelle

Solomon, Edward I.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00226a047

We report the assignment of LF (ligand field) transitions, for a Rb model complex (Fe(SR)^- R=2,3,5,6-Me4C6H), with single crystal polarized absorption and magnetic circular dichroism (MCD).We also experimentally test Griffith's ZFS (zero field splitting) model.

Full text of DOI:10.1021/ja00226a047

Products guided by the article

Product name:{PPh₄}{FeCl₄}

Cas No:30862-67-0

R&D Labs maybe for 30862-67-0

Shandong Xiangde Biotechnology Co., Ltd

Contact:+86 -15066639877

Address:Sanba street
Kaymossy BioChem Tech Co., Ltd

website:http://www.kaimosi.com

Contact:0571-87191913/0571-87199097

Address:Room 215, Building 3rd, No.288 Ningxia Road, Qingdao city, China
C-LAB Chemievermittlung GmbH

Contact:+49-9398-993127

Address:Untertorstr. 27
Tianjin Tongde Biological Technology Co., Ltd.

Contact:86-22-23309138

Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
KA-SHING Business Trade Macau Co., Ltd.

Contact:00853-28430045

Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao

Relevant to this article

A new convenient four-component synthesis of 6-amino-2H,4H-pyrano[2,3-c] pyrazole-5-carbonitriles and one-pot synthesis of 6′-amino-5′-cyano- 1,2-dihydrospiro- [(3H)-indole-3,4′-(4′H)-pyrano[2,3-c]pyrazol]-2- ones

Doi:10.1007/s11172-009-0328-4
(2009)
Syntheses and structural studies of five- and six-coordinate o-halophenyl derivatives of ruthenium(II) and osmium(II)

Doi:10.1016/S0022-328X(00)00170-4
(2000)
Doi:10.1366/000370272774352632
(1972)
Gas-Phase Substituent Effects in Highly Electron-Deficient Systems. I. Intrinsic Stabilities of 1-Aryl-1-(trifluoromethyl)ethyl Cations

Doi:10.1246/bcsj.69.3273
(1996)
Doi:10.1021/jo00819a026
(1971)
Fluxional behavior of indenyl-derived ytterbocene(II) complexes. The SiHR₂ group as a NMR spectroscopic probe

Doi:10.1021/om000324w
(2000)

Article Doi