Journal of Organometallic Chemistry p. 213 - 224 (1985)
Update date:2022-08-05
Topics:
Davies, Stephen G.
Dordor-Hedgecock, Isabelle M.
Warner, Peter
The aluminium anolate derived from the iron acetyl complex <(η5-C5H5)Fe(CO)(PPh3)COCH3>, in contrast to the lithium enolate, undergoes highly strereoselective aldol reactions with aldehydes to generate RR,SS-β-hydroxyacyl complexes which on decomlexation liberate β-hydroxy acids or esters.Determination of the molecular structure of RR,SS-<(η5-C5H5)Fe(CO)(PPh3)(COCH2CH(OH)CH2CH3> allowed assignment of the relative configuration of the new chiral centre.
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