Synthesis and Some Reactions of 3,4,5,6-Tetrahydro-3,6-dimethyl-2,6-methano-3-benzazocin-1(2H)-one (2,5-Dimethyl-8-oxo-6,7-benzomorphan)

DOI: 10.1039/P19800002374

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2374 - 2379 (1980)

Update date:2022-08-04

Topics:

Authors:

Carr, David

Iddon, Brian

Suschitzky, Hans

Parfitt, Robert T.

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Article abstract of DOI:10.1039/P19800002374

In a Beckmann rearrangement the oxime of the title compound (1) gave 1,3,4,5,6,7-hexahydro-4,7-dimethyl-3,7-methano-1,4-benzodiazonin-2-one (3).Hydrolysis of this product (3) with hydrochloric acid gave 4-(2-aminophenyl)-1,4-dimethylpiperidine-2-carboxyli

Full text of DOI:10.1039/P19800002374

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