Tetrahedron Asymmetry p. 3263 - 3267 (2000)
Update date:2022-08-03
Topics:
Pitacco, Giuliana
O Santi, Andrea Sessanta
Valentin, Ennio
The possibility of using enzymes for the kinetic resolution of an α-methylene-γ-lactone was explored. The probe molecule, ethyl 2-methyl-4-methylene-tetrahydro-5-oxo-2-furancarboxylate was successfully resolved with Porcine pancreatic lipase and Candida rugosa lipase, in the presence of a cosolvent, leading to both enantiomers of the corresponding acid with high enantiomeric excesses. Copyright (C) 2000 Elsevier Science Ltd.
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