1,1-dihydroperfluoroalkylations of nucleophiles with (1,1-dihydroperfluoroalkyl)phenyliodonium triflates

DOI: 10.1016/S0022-1139(00)80536-9

Source and publish data:

Journal of Fluorine Chemistry p. 231 - 236 (1986)

Update date:2022-08-03

Topics: Regioselectivity Column chromatography Yield NMR spectroscopy Mass spectrometry nucleophiles TLC (thin-layer chromatography) Anhydrous conditions Oxidative Addition Reductive Elimination Reaction Mechanism Solvent Effects Stereoselectivity Catalysis Perfluoroalkyl Groups Hypervalent Iodine Compounds Triflates Electrophilic fluorination

Authors:

Umemoto, Teruo

Gotoh, Yoshihiko

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Article abstract of DOI:10.1016/S0022-1139(00)80536-9

It was demonstrated that (1,1-dihydroperfluoroalkyl)phenyliodonium triflates (FMITS) served as very useful sources of 1,1- dihydroperfluoroalkyl cations. With a variety of nucleophiles, the corresponding fluoroalkyl derivatives were obtained.

Full text of DOI:10.1016/S0022-1139(00)80536-9

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