Journal of Fluorine Chemistry p. 231 - 236 (1986)
Update date:2022-08-03
Topics: Regioselectivity Column chromatography Yield NMR spectroscopy Mass spectrometry nucleophiles TLC (thin-layer chromatography) Anhydrous conditions Oxidative Addition Reductive Elimination Reaction Mechanism Solvent Effects Stereoselectivity Catalysis Perfluoroalkyl Groups Hypervalent Iodine Compounds Triflates Electrophilic fluorination
Umemoto, Teruo
Gotoh, Yoshihiko
It was demonstrated that (1,1-dihydroperfluoroalkyl)phenyliodonium triflates (FMITS) served as very useful sources of 1,1- dihydroperfluoroalkyl cations. With a variety of nucleophiles, the corresponding fluoroalkyl derivatives were obtained.
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