Journal of Organic Chemistry p. 2270 - 2274 (2008)
Update date:2022-07-30
Topics:
Wang, Zhi
Cui, Yong-Tao
Xu, Zhao-Bing
Qu, Jin
Effective hydrolysis of epoxides and aziridines was conducted by heating them in water at 60 or 100 °C. Other types of nucleophile such as amines, sodium azide, and thiophenol could also efficiently open epoxides and aziridines in hot water. It was proposed that hot water acted as a modest acid catalyst, reactant, and solvent in the hydrolysis reactions.
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