Journal of the American Chemical Society p. 615 - 619 (1981)
Update date:2022-07-31
Topics:
Beckwith, A. L. J.
Easton, C. J.
An EPR technique and a method involving the gas chromatographic determination of the relative rates of consumption of substrates have been employed to measure the relative rates of hydrogen atom abstraction by tert-butoxy radicals from various substituted 1,3-dioxanes.The high relative reactivities of dioxanes equitorially substituted at C-2 as compared with their axially substituted epimers are attributed to the favorable stereoelectronic interactions in the former between the axial C-H bonds and adjacent oxygen lone pairs.The effects of methoxy substituents on the relative reactivities of cyclic ethers have been similarly rationalized.The photoinduced reaction between benzophenone and the methoxydioxane (8) has been shown to be reversible.
View MoreContact:86-607-68073220
Address:1 ave na road jiahua st
Shantou Baokang Pharmaceutical Co., Ltd.
Contact:+86-754-88873487
Address:5/F B Block Huangshan Bldg Huangshan Rd Shantou
Nanjing Chemlin Chemical Co., Ltd.
website:http://www.echemlin.cn
Contact:+86-25-83697070
Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
Contact:+86-158-5814-5714
Address:No.9 YanAn Road,Hangzhou,Zhejiang,China
Contact:86-511-85210668 0511-85210668, 85210818, 85210898
Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Doi:10.1021/jo9821022
(1999)Doi:10.1016/j.jfluchem.2006.09.007
(2006)Doi:10.1016/S0040-4020(99)00172-6
(1999)Doi:10.1039/a809652j
(1999)Doi:10.1016/j.tet.2017.05.008
(2017)Doi:10.1021/ja00406a030
(1981)
