
Chemistry Letters p. 1221 - 1224 (1987)
Update date:2022-08-04
Topics:
ANPO, Masakazu
H-D exchange between deuterated surface hydroxyl groups and excited triplet acetone has been observed on porous Vycor glass, proceeding via surface hydroxyl group-assited photoenolization of acetone.This chemical process evidences that surface hydroxyl groups play a significant role in determining the fate of the excited triplet acetone adsorbed on Vycor glass by a strong hydrogen bonding.
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