The mild oxidation of nitrile oxides affords a convenient entry to nitrosocarbonyl intermediates, versatile tools in organic syntheses

DOI: 10.1016/S0040-4020(99)00574-8

Source and publish data:

Tetrahedron p. 10497 - 10510 (1999)

Update date:2022-08-03

Topics:

Authors:

Quadrelli

Mella Mella

Gamba Invernizzi

Caramella

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Article abstract of DOI:10.1016/S0040-4020(99)00574-8

Nitrile oxides are oxidized by tertiary amine N-oxides in different solvents at room temperature to afford in the presence of dienes nitrosocarbonyl adducts in fair yields. The mild conditions used in oxidizing a variety of nitrile oxides promise a wide application of this method in synthetic processes.

Full text of DOI:10.1016/S0040-4020(99)00574-8

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