REACTIVITY OF THE TETRAHYDROBORATE COPPER(I) COMPLEXES 2-BH4)> (R = Ph, Cy) TOWARD CO2, COS, AND SCNPh

DOI: 10.1016/0022-328X(83)87031-4

Source and publish data:

Journal of Organometallic Chemistry p. C27 - C30 (1983)

Update date:2022-08-05

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Authors:

Bianchini, Claudio

Ghilardi, Carlo A.

Meli, Andrea

Midollini, Stefano

Orlandini, Annabella

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Article abstract of DOI:10.1016/0022-328X(83)87031-4

CO2, COS, and SCNPh react under very mild conditions with the copper(I)-tetrahydroborate complexes <(PR3)2Cu(η²-BH4)> (R = Ph, Cy); CO2 and COS give the complexes <(PR3)2Cu(η²-O2CH)> and <(PR3)2Cu(η²-OSCH)> respectively, w

Full text of DOI:10.1016/0022-328X(83)87031-4

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