Inorganic Chemistry p. 243 - 247 (1970)
Update date:2022-09-26
Topics:
Oliver
Graham
At low temperatures C5Hr5Rh(CO)L, 1 (L = P(CH3)2C6H5), reacts with Cl2, Br2, CH3COBr, and CF3COCl forming isolable [C5H5Rh(CO)LX] +X- or [C5H5Rh(CO)L(COR)] +X- which were converted to their more stable tetraphenylboron salts. At room temperature the ionic dihalides lose CO forming neutral C5H5RhLX2. Alkyl halides (CH3Cl, CH3Br, CH3I, C3H5Cl) react with 1 forming acyl derivatives C5H5RhL(COR)X in a reaction thought to proceed via ionic [C5H5Rh(CO)LR] +X-.
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Doi:10.1016/S0960-894X(02)00138-5
(2002)Doi:10.1021/jo00169a047
(1983)Doi:10.1246/bcsj.44.1112
(1971)Doi:10.1002/1099-0690(200301)2003:1<155::AID-EJOC155>3.0.CO;2-S
(2003)Doi:10.1021/ol015520t
(2001)Doi:10.1016/S0040-4039(01)96740-1
(1971)
