Journal of the Chemical Society. Chemical communications p. 1548 - 1549 (1984)
Update date:2022-08-03
Topics:
Reitz, Allen B.
Maryanoff, E.
Wittig-reaction intermediates derived from hexanal and (γ-oxidopropylidene)triphenylphosphorane, (1), are freely reversible, as indicated by significant quantities of cross-over products from a second aldehyde (octanal); such a result may account for anomalously enhanced E stereoselectivity in the reaction of γ- and β-oxido ylides with aliphatic aldehydes.
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