Cobalt-catalyzed ortho-alkenylation of aromatic aldimines via chelation-assisted C-H bond activation

DOI: 10.1016/j.tet.2013.02.092

Source and publish data:

Tetrahedron p. 4459 - 4465 (2013)

Update date:2022-08-05

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Authors:

Yamakawa, Takeshi

Yoshikai, Naohiko

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Article abstract of DOI:10.1016/j.tet.2013.02.092

An ortho-alkenylation reaction of an aromatic aldimine with an internal alkyne is efficiently promoted by a cobalt catalyst generated from CoBr ₂, triarylphosphine, and ⁱPrMgBr. The reaction takes place under mild room-temperature co

Full text of DOI:10.1016/j.tet.2013.02.092

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