Convenient synthesis of 2,4-cyclohexadien-1-ones by regioselective methylthiomethylation of phenols

DOI: 10.1248/cpb.41.439

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 439 - 444 (1993)

Update date:2022-08-02

Topics: Phenols Regioselective convenient synthesis

Authors:

Katayama

Watanabe

Yamauchi

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Article abstract of DOI:10.1248/cpb.41.439

A convenient synthesis of a variety of 2,4-cyclohexadien-1-ones 3-7 is deseribed. Reaction of various phenols 2 having appropriate substituents with an excess of S,S-dimethylsuccinimidosulfonium chloride (Corey-Kim reagent, 1) in the presence of triethyla

Full text of DOI:10.1248/cpb.41.439

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