Journal of the American Chemical Society p. 3243 - 3246 (2001)
Update date:2022-08-02
Topics: Total synthesis Chemical reactions Nucleophilic substitution Oxidative Cyclization Chromatographic purification Palladium-catalyzed coupling
Lee, Jae Chol
Cha, Jin Kun
A unified, ready access to the tropoloisoquinoline alkaloids imerubrine (1), grandirubrine (2), and isoimerubrine (3) is delineated and features sequential application of the intramolecular Diels - Alder reaction of an acetylene-tethered oxazole and the [
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