Journal of the Chemical Society, Dalton Transactions p. 1734 - 1736 (1980)
Update date:2022-08-05
Topics:
Edwards, Anthony J.
Hana, Arsein A. K.
The structure of the title adduct has been determined by heavy-atom method from 1 451 diffractometer reflections and refined by full-matrix least-squares methods to R 0.074.Crystals are monoclinic, space group P21/c, with unit-cell dimensions a = 5.72(1), b = 9.96(1), c = 12.56(2) Angstroem, β = 101.7(2)deg.The solid adduct exists as dimers with two antimony and two iodine atoms at the corners of a rhombus, linked by asymmetric, angular oxygen bridges, with Sb-O 2.05 and I-O 1.80 Angstroem.Both the SbF4O2 and IF4O2 units have distorted octahedral geometries with cis oxygen bridges, and with a greater distortion in the antimony unit.This can be correlated with a contribution to the structure from the ionic form (SbF4)+(IF4O2)-.The adduct has a very similar structure to pentafluorides typified by RuF5, based on an approximate hexagonal close-packing of the light atoms.
Yancheng Creator Chemical Co., Ltd
Contact:0086-515-88710008 88710068 88710858 88710868
Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City
Changzhou Litong Chemical Co., Ltd.
website:http://www.litonchem.com/
Contact:+86-519-86301238
Address:Laoba Rd, Hutang town Changzhou Jiangsu
Hangzhou Dingyan Chem Co., Ltd
website:http://www.dingyanchem.com
Contact:86-571-87157530
Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004
Hangzhou Taiyan Trading Co., Ltd(expird)
Contact:+86-13777583958
Address:NO.63, Xingyi Street, Xihu District, Hangzhou, Zhejiang, China
Contact:86-10-62664360
Address:Building 10,No.18 AnNingZhuang East Road, GuangHua Pioneer Park,HaiDian District, BeiJing China
Doi:10.1016/j.tetasy.2011.05.008
(2011)Doi:10.1016/S0039-128X(96)00202-4
(1996)Doi:10.7164/antibiotics.54.297
(2001)Doi:10.1021/jo00975a022
(1972)Doi:10.3987/COM-09-S(S)45
(2010)Doi:10.1016/S0022-328X(00)00750-6
(2001)
